下辽河平原景观格局演变与预测分析

以下辽河平原为研究对象,选取1980年、2010年和2018年Landsat TM/ETM+OLI卫星图像进行解译,得到3期土地利用数据,定量分析下辽河平原近40年土地利用时空变化特征.结合地形、交通通达度及限制转化因子采用FLUS(Future Land Use Simulation)模型对流域未来土地利用变化情景及景观格局进行了预测.结果表明:1980-2018年水田、林地、草地、沼泽面积均减少,其中水田面积减少量最大,占比减少了8.59％,旱地、水域和城镇的面积均有所上升,旱地的增长面积最大,占比增加了6.19％;水田、林地、水域转入为旱地面积最大,旱地转出为建设用地面积最大;1980-2018年景观格局发生了较大变化,景观的破碎化程度降低,斑块之间的连通度、聚集程度升高,土地利用的集约化程度增大;2018-2040年,下辽河平原建设用地和水田的变化面积最大,城市化过程更加显著,景观的多样性及空间异质性降低,人类对环境的干扰能力变大.     

GNSS多天线基线网单历元模糊度同步解算法

提出多天线基线网单历元模糊度同步解算法，其具体实现步骤为：1）根据宽巷组合模糊度易于固定的优点，采用附加已知基线长度约束法同步解算各基线的宽巷模糊度，得到dm~cm级精度的近似基线分量；2）将解算得到的各近似基线分量作为约束，同步解算各基线的基频模糊度，以获取mm级精度的基线矢量。该方法的关键在于检验各历元宽巷模糊度解算的正确性，以获取可靠的近似基线分量，为解算各基线的基频模糊度提供准确的基线先验信息。由于动态情况下各历元观测信息比较少，单纯依赖ratio检验不可靠，提出结合基线误差、单位权中误差、基线网模糊度闭合环及ratio值等对多组宽巷模糊度进行检验，避免ratio值设置不当导致模糊度检验中发生纳伪和弃真问题。实测数据结果证明，该处理方法使得模糊度解算的成功率提高1%~2%，可以获取移动平台更丰富的导航信息，提高其服务能力。     

Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.     

Temporal and Spatial Dynamics Analysis of Grassland Ecosystem Pressure in Kazakhstan

Affected by climate change and policy factors, Kazakhstan is the country with the most severe ecological degradation and grassland conflicts in Central Asia. Therefore, studying the state of grassland carrying resources in Kazakhstan is particularly important for understanding the responses of grassland ecosystems to climate change and human activities. Based on Kazakhstan's remote sensing data and animal husbandry statistics, this study analyzes the patterns of changes in grassland ecosystems in Kazakhstan based on the supply and consumption of these ecosystems. The results show that: 1) From 2003 to 2017, the number of livestock raised in Kazakhstan showed a trend of sustained and steady growth. Due to freezing damage, the scale of livestock farming decreased in 2011, but a spatial difference in the livestock farming structure was not obvious. 2) The fluctuation of grassland supply in Kazakhstan has increased, while the consumption due to animal husbandry has also continued to increase, resulting in an increasing pressure on the grassland carrying capacity. 3) Between 2003 and 2017, the overall grassland carrying status of Kazakhstan have been abundant, but the grassland carrying pressure index has shown a steadily increasing trend, the grassland carrying pressure is growing, and it is mainly determined by grassland productivity. The greater pressure in lower Kyzylorda state, the southern Kazakhstan state of the cultivated land and the northern Kazakhstan state has gradually expanded to include the agro-pastoral zone and the semi-desert zone.     

黔北镇远牛蹄塘组黑色页岩沉积环境与有机质富集关系

通过矿物组分、主量元素、微量元素、碳氧同位素等特征，分析了黔北地区镇远县ZX井牛蹄塘组黑色页岩的岩相类型和不同岩相页岩的沉积环境及其与有机质富集间的关系。结果表明，牛蹄塘组下段以硅质页岩为主，TOC含量4. 96%~10. 10%；上段以富泥硅质页岩为主，TOC含量1. 43%~9. 04%。下段硅质页岩沉积于水流停滞的深水陆棚环境，沉积古水体为贫氧的还原状态；上段富泥硅质页岩沉积时期，仍为贫氧的还原环境，但水体滞留程度、还原性较下段硅质页岩沉积期弱。贫氧的还原环境是影响牛蹄塘组黑色页岩有机质富集的主要因素，热液作用和陆源碎屑对牛蹄塘组黑色页岩有机质富集的影响较小。     

金矿立体地球化学探测模型与深部钻探验证

深部资源地球化学探测科学问题的的焦点是元素大深度垂向迁移机理和立体地球化学探测模型的建立。本文以胶东蚀变岩型金矿和贵州水银洞卡林型金矿钻孔岩芯和地表联合取样获得的数据, 建立千米深度立体地球化学探测模型。蚀变岩型金矿立体地球化学模型显示, Au、S和Hg与金矿密切相关, 分布模式既有相似性又有差异性, Au的立体几何分布模式兼具矿化剂元素S和远程指示元素Hg的双重特征, 金异常和矿化剂元素硫与矿体倾斜方向一致, 反映了成矿过程中流体沿控矿构造的轴向运移; 金异常与类气体元素汞在垂向上一致, 而且出现从矿体到地表的连续贯通式异常, 反映了流体沿微裂隙和纳米孔的垂向迁移。卡林型金矿立体地球化学模型显示, Au、As、Sb、Hg、Tl和S在不整合面都显示高含量特征, 与深部层状主矿体分布一致; 在矿体上覆地层中都存在弱异常, 显示了明显的成矿流体沿隐伏微小断裂垂向迁移特点; 所不同的是Sb和Tl元素在不整合面附近显示了最高的元素含量, 而Sb和Hg在近地表均显示了明显高的异常特征。立体几何模型清晰地显示了矿体的展布特征和范围, 而且金及其伴生元素垂向迁移在地表形成清晰异常, 为利用金及伴生元素和矿化剂元素进行深部矿体三维预测提供了重要依据, 对指导深部金矿勘查发挥了重要作用。针对胶东蚀变岩型金矿地表完全被土壤覆盖区的穿透性地球化学微细粒级土壤采样, 金属活动态提取分析圈定的异常, 经深部钻探验证, 胶东焦家成矿带五一村3200 m钻探, 在2428.00~3234.16 m深度发现6层矿化体, 其中高品位矿体位于2854 m深度; 上宫金矿地表基岩出露, 采集断层泥或裂隙岩石样品, 可以清晰探测深部异常, 经2000 m钻探, 在1312 m处发现高品位金铅锌银矿体; 贵州水银洞采集地表细粒级土壤, 能够直接有效地揭示深部金矿体, 经500~1500 m钻探验证, 在300~1500 m深度新增金资源量203 t。     

BDS卫星差分码偏差稳定性分析及其短期预报

利用MGEX(multi-GNSS experiment)发布的BDS卫星差分码偏差(differential code bias, DCB)产品，比较分析不同太阳活动水平下BDS卫星DCB产品的稳定性变化特性，并采用差分自回归移动平均(auto-regressive integrated moving average, ARIMA)时间序列预测模型，实现不同太阳活动水平下BDS卫星DCB的短期预报。结果表明，在太阳活动高年，BDS卫星DCB日解值稳定度、月稳定性均明显低于太阳活动低年，且不同卫星星座类型的BDS卫星DCB稳定性也存在差异；ARIMA时间序列预报结果与MGEX发布值符合程度较好，优于多项式拟合法预测结果。     

碳化对加填料氯氧镁胶凝材料力学性能的影响

以添加不同掺量填料的氯氧镁水泥(MOC)试件为基体,在空气和碳化箱中分别养护至规定龄期,研究碳化对掺加填料MOC力学性能的影响,并与空气环境进行对比,运用XRD和SEM分析碳化后水化产物和微观结构的变化规律。结果表明,28 d龄期内,随着填料掺量的增加MOC试件碳化后的抗折强度均有所增加,碳化后的抗压强度均有提升,碳化过程反应生成了MgCO_3,不同碳化龄期的主要物相均为5Mg(OH)_2·MgCl_2·8H_2O(5相),而掺加填料不影响MOC的水化产物的组成。     

新疆东天山觉罗塔格带中康古尔金矿床成因的再认识

东天山觉罗塔格构造带中康古尔金矿因其独特的成矿地质特征，成因一直备受争议。文章立足于康古尔金矿地质特征，结合前人的研究资料，通过探讨觉罗塔格带的构造演化，重新审视康古尔金矿的成因。笔者总结了觉罗塔格构造带晚古生代地层时代及火山-沉积建造特征，认为晚古生代早期大洋板块向北俯冲，发育奥陶纪-泥盆纪弧火山岩及火山-沉积岩系，石炭纪康古尔洋发生双向洋-陆俯冲，在两侧形成对称岛弧带，局部平稳拉张环境为铜-铅-锌-金成矿的有利环境。野外地质观察及室内研究结果表明其成因不仅仅与韧性剪切作用有关。康古尔金矿体位于海相安山岩、凝灰岩的交替部位，上部富金-中部铅锌-下部富铜的金属分带特征，与VMS矿床特征一致。矿体呈板状且与围岩截然接触，明显受挤压变形的网脉状矿化表明矿体形成早于韧性剪切作用。矿床地球化学特征表明，康古尔金矿成矿作用具有多期多阶段性。通过详细对比康古尔金矿和造山型金矿、小热泉子VMS铜矿的特征，笔者认为康古尔金矿具有原生VMS矿床的特征，并且被二叠纪韧性变形所改造，为喷流沉积-变质热液改造型富金多金属矿床。